| 黄永仲.甲醇柴油双燃料发动机二氧化氮排放后处理方案研究[J].内燃机工程,2019,40(4):72-77. |
| Research on Aftertreatment Solution to Nitrogen Dioxide Emissions from a Diesel/Methanol Engine |
| DOI：10.13949/j.cnki.nrjgc.2019.04.011 |
| Key Words:diesel engine nitrogen dioxide methanol formaldehyde diesel oxidation catalysts（DOC） selective catalytic reduction(SCR) |
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| Abstract:The effect of diesel oxidation catalyst(DOC) and its combination with selective catalytic reduction(SCR) system on NO2, formaldehyde and methanol emissions from a diesel/methanol engine was studied. Results show that the use of DOC in the dual fuel engine can make NO2 ratio reach the level of general diesel emissions and significantly reduce methanol emissions, but does not ideally purify formaldehyde. Under the condition of maintaining the conventional NO2 ratio level of diesel-engines, the SCR+DOC scheme can completely eliminate the formaldehyde and methanol emissions from the dual fuel engine. According to the variation of NO2 ratio in each stage, the standard Gibbs free energy change of the relevant reversible reaction at combustion temperature and exhaust temperature has been analyzed successively, and the main reactions and directions of each stage were clarified. Moreover, the possible reasons for the complete oxidation of methanol by the SCR+DOC scheme were also discussed together with related studies. |
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